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Within the framework of equilibrium statistical mechanics the free energy of a phase gives a measure of its associated probabilistic weight. In order to determine phase boundaries one must then determine the conditions under which the free energy difference (FED) between two phases is zero. The underlying complexity usually rules out any analytical approaches to the problem, and one must theref...
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ژورنال
عنوان ژورنال: Nature
سال: 1964
ISSN: 0028-0836,1476-4687
DOI: 10.1038/204727a0